[pam-users] RO2 chemistry paper

pam-users aerodyne-pam-users at aerodyne.com
Mon Sep 24 23:53:42 EDT 2018


Link to the paper:
https://www.atmos-chem-phys-discuss.net/acp-2018-952/

Also the RO2 Fate Estimators (for general use and for OFR) are available in
the Supplement:
https://www.atmos-chem-phys-discuss.net/acp-2018-952/acp-2018-952-supplement.zip

Zhe

On Mon, Sep 24, 2018 at 9:24 PM pam-users <aerodyne-pam-users at aerodyne.com>
wrote:

> Dear all,
>
> Our paper on RO2 chemistry in OFRs just appeared in ACPD today. As most of
> you know, RO2 are among the most critical intermediates in atmospheric
> oxidation of organics, and their fate determines the product molecules. For
> some OFR applications where it is important to produce the same molecules
> in the OFR as in the atmosphere, it is important to try to keep the RO2
> chemical regime similar. The paper includes the details of the basis for
> the limitations on the operating space of the PAM (particularly at low NO)
> that were discussed at the PAM Users Meeting as well as in my talk at IAC a
> couple of weeks ago.
>
> Please note that, just as we discussed at the Users Meeting, this paper
> contains information for users who care about which SOA (or gas-phase)
> molecules are actually produced. This will generally matter wanting to
> produce atmospherically realistic SOA for studying e.g. toxicology, light
> absorption, and physico-chemical properties. For users that only want to
> use an OFR to produce a complex mixture of oxidized species to test
> instruments or for other purposes, these limitations may not apply, or not
> as strictly.
>
> If you have any questions or comments on the paper, please let us know.
>
> Cheers,
> Zhe
>
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