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<p class="MsoNormal">Hartikainen, A., Ihalainen, M., Shukla, D., Rohkamp, M., Mukherjee, A., He, Q., Piel, S., Virkkula, A., Li, D., Kokkola, T., Jeong, S., Koponen, H., Etzien, U., Das, A., Luoma, K., Schwalb, L., Gröger, T., Barth, A., Sklorz, M., Streibel,
T., Czech, H., Gündling, B., Kalberer, M., Buchholz, B., Hupfer, A., Adam, T., Hohaus, T., Øvrevik, J., Zimmermann, R., and Sippula, O.: Photochemical aging of aviation emissions: transformation of chemical and physical properties of exhaust emissions from
a laboratory-scale jet engine combustion chamber, EGUsphere [preprint], https://doi.org/10.5194/egusphere-2024-3836, 2025 <o:p></o:p></p>
<p class="MsoNormal"><o:p> </o:p></p>
<p class="MsoNormal"><b>Abstract</b>. Aviation is an important source of urban air pollution, but the impacts of photochemical processing on the exhaust emissions remain insufficiently characterized. Here, the physical-chemical properties of fresh and photochemically
aged emissions from a laboratory-scale jet engine burner operated with JP-8 kerosene were studied in detail with a range of online and offline methods. The fresh emissions contained high amounts of organic matter present predominantly in the gaseous phase.
Photochemical aging in an oxidation flow reactor caused substantial formation of oxidized organic aerosol, increasing the particle mass by approximately 300 times. During aging, aromatic hydrocarbons and alkanes in the gas-phase decayed, while gas-phase oxidation
products, such as small carbonyls and oxygenated aromatics increased. The composition of organic matter became more complex by photochemical processing, with oxidation state increasingly growing throughout the addressed exposure range (equivalent to 0.2 to
7 days in atmosphere) with a ΔH:C/ΔO:C slope of -0.54. Simultaneously, the near-UV wavelength absorption by the particles increased due to enhanced particulate mass. The imaginary refractory indices of organic particulate matter were 0.0071 and 0.00013 at
the wavelength of 520 nm for the fresh and photochemically processed particles, respectively, indicating secondary production of weakly absorbing brown carbon. The direct radiative forcing by the exhaust particles was estimated by a Mie-model, which revealed
a prominent shift from warming to cooling climate effect upon photochemical aging. The results highlight the importance in considering secondary aerosol formation when assessing the environmental impacts of aviation.<o:p></o:p></p>
<p class="MsoNormal"><o:p> </o:p></p>
<p class="MsoNormal"><a href="https://sites.google.com/site/pamwiki/publications-using-other-oxidation-flow-reactors">PAM Wiki - Publications Using Other Oxidation Flow Reactors</a><o:p></o:p></p>
<p class="MsoNormal"><o:p> </o:p></p>
<p class="MsoNormal"><span style="mso-ligatures:none">Andrew Lambe<o:p></o:p></span></p>
<p class="MsoNormal"><span style="mso-ligatures:none">Principal Scientist<o:p></o:p></span></p>
<p class="MsoNormal"><span style="mso-ligatures:none">Aerodyne Research, Inc. <o:p>
</o:p></span></p>
<p class="MsoNormal"><o:p> </o:p></p>
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